Petroleum Refinery Engineering

Q1:

Cracking is

A an exothermic reaction.

B an endothermic reaction.

C favoured at very low temperature.

D none of these.

ANS:B - an endothermic reaction.

Cracking is generally considered to be an endothermic reaction. Here’s an explanation:

  • Cracking: In petroleum refining, cracking refers to the process of breaking down large hydrocarbon molecules into smaller, more valuable molecules. This is typically achieved by heating the hydrocarbons to high temperatures.
  • Endothermic Reaction: An endothermic reaction absorbs heat from its surroundings to proceed. In the case of cracking, the breaking of strong carbon-carbon bonds in larger molecules requires energy input (heat) to break these bonds and form smaller molecules.
  • Temperature Dependence: Cracking is favored at high temperatures because higher temperatures provide the necessary energy to break the carbon-carbon bonds efficiently. Therefore, it is not favored at very low temperatures where insufficient energy is available to initiate and sustain the cracking process.
  • Practical Application: Industrial cracking processes such as catalytic cracking and steam cracking are carried out at temperatures ranging from several hundred to over a thousand degrees Celsius to optimize the yield of desired products such as gasoline, diesel, and petrochemical feedstocks.
Therefore, cracking is correctly described as an endothermic reaction because it requires heat input to break down large hydrocarbon molecules into smaller ones.



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