Petroleum Refinery Engineering

Q1:

In catalytic cracking process, olefins crack __________ times faster than in thermal cracking process.

A 100

B 200-300

C 1000-10000

D 10

ANS:C - 1000-10000

In the catalytic cracking process, olefins crack 10 times faster than in the thermal cracking process. Here’s an explanation:

  • Catalytic Cracking: Catalytic cracking is a refining process where high-molecular-weight hydrocarbons are broken down into lighter, more valuable products (such as gasoline and diesel) using a catalyst. The catalyst facilitates the cracking reaction at lower temperatures compared to thermal cracking.
  • Olefins: Olefins, which are unsaturated hydrocarbons with at least one carbon-carbon double bond (e.g., ethylene, propylene), crack more rapidly in the presence of a catalyst. The catalytic action lowers the activation energy required for the cracking reaction, allowing olefins to break apart into smaller molecules more efficiently.
  • Comparison with Thermal Cracking: In thermal cracking (without a catalyst), the cracking of olefins occurs more slowly because it relies solely on high temperatures to break chemical bonds. The absence of a catalyst means that the cracking reactions are less selective and require higher temperatures to achieve comparable rates of cracking.
Therefore, olefins crack approximately 10 times faster in catalytic cracking compared to thermal cracking processes, highlighting the efficiency and selectivity of catalytic cracking in producing valuable hydrocarbon products from heavier feedstocks.



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