Chemical Process - Engineering

Q1:

Chemical formula of oleum is

A H2SO3

B H2SO4

C H2S2O7

D H2SO7

ANS:C - H2S2O7

The chemical formula of oleum is H₂S₂O₇. The chemical formula of oleum is H₂S₂O₇, and here’s an explanation of its composition and significance:

Composition:

  1. Sulfuric Acid Derivative:
    • Oleum is a solution of sulfur trioxide (SO₃) in sulfuric acid (H₂SO₄). It can be seen as a concentrated form of sulfuric acid containing extra sulfur trioxide.
  2. Molecular Structure:
    • The formula H₂S₂O₇ indicates that oleum consists of two sulfur atoms, seven oxygen atoms, and two hydrogen atoms. This structure reflects its acidic nature and high sulfur content.

Properties:

  1. Highly Corrosive:
    • Oleum is a strong acid and is highly corrosive, capable of reacting violently with water and organic materials.
  2. Viscous Liquid:
    • It appears as a thick, oily liquid, which can vary in concentration depending on the amount of dissolved SO₃.

Production:

  1. Manufacturing Process:
    • Oleum is typically produced during the contact process for sulfuric acid production, where sulfur dioxide is oxidized to sulfur trioxide, which is then absorbed in existing sulfuric acid.

Applications:

  1. Industrial Use:
    • Oleum is used in the production of sulfuric acid, in chemical synthesis, and as a dehydrating agent in various chemical processes.
  2. Sulfonation:
    • It is used in the sulfonation of organic compounds, important in the manufacturing of detergents, dyes, and pharmaceuticals.

Summary:

In summary, the chemical formula H₂S₂O₇ for oleum signifies its role as a concentrated form of sulfuric acid with significant industrial applications, characterized by its corrosive properties and complex structure.