Chemical Engineering Basics - Engineering

Q1:

Eutectoid composition of carbon steel at room temperature is

A cementite

B pearlite

C martensite

D ferrite

ANS:B - pearlite

The eutectoid composition of carbon steel at room temperature forms pearlite. Eutectoid steel contains approximately 0.8% carbon by weight. When this steel is cooled from a high temperature to room temperature, it undergoes a phase transformation known as eutectoid transformation. During this transformation, the austenite phase (which exists at high temperatures) decomposes into two phases: ferrite (a solid solution of carbon in iron) and cementite (an intermetallic compound of iron and carbon with the chemical formula Fe₃C). The microstructure resulting from the eutectoid transformation consists of alternating layers of ferrite and cementite, which collectively form a lamellar structure known as pearlite. Therefore, pearlite is the phase that predominates at room temperature in eutectoid carbon steel. To clarify further, the options given are as follows:

  • Cementite: A phase composed primarily of iron and carbon, with the chemical formula Fe₃C. It is a component of pearlite.
  • Pearlite: A lamellar structure consisting of alternating layers of ferrite and cementite, which forms during the eutectoid transformation in steel.
  • Martensite: A metastable phase formed by rapid cooling of austenite, characterized by a highly strained and distorted lattice structure.
  • Ferrite: A solid solution of carbon in iron, which is one of the phases formed during the eutectoid transformation in steel.
Among these options, pearlite is the correct phase that represents the eutectoid composition of carbon steel at room temperature.