

Fertiliser Technology - Engineering
Q1: Heating a mixture of phosphate rock, coke and sand in an electric furnace producesA phosphoric acid
B ammonium phosphate
C phosphorous
D superphosphate
ANS:C - phosphorous Heating a mixture of phosphate rock, coke, and sand in an electric furnace typically produces phosphorus. The process involves the reduction of phosphate rock (which is mainly fluorapatite, Ca5(PO4)3F) with carbon (from coke) to produce elemental phosphorus vapor, along with carbon monoxide gas. This process is commonly known as the electric furnace method or the thermal process for phosphorus production. The chemical reaction involved in this process can be represented as follows: 2πΆπ5(ππ4)3πΉ+10πΆ+10πππ2→10πΆππππ3+10πΆπ+π42Ca5(PO4)3F+10C+10SiO2→10CaSiO3+10CO+P4 In this reaction, phosphate rock reacts with carbon and silicon dioxide (from sand) to produce calcium silicate slag (CaSiO3), carbon monoxide (CO), and elemental phosphorus (P4). The elemental phosphorus vapor is then collected and condensed into a liquid form, which can be further processed to produce various phosphorus-based chemicals, including phosphoric acid and phosphate fertilizers. However, the direct product of heating the mixture in an electric furnace is elemental phosphorus, not phosphoric acid or other phosphate compounds. Phosphorus is a chemical element with the symbol P and atomic number 15. It is a non-metallic element that is essential for life, as it plays crucial roles in biological processes, such as DNA and RNA synthesis, energy transfer (through ATP), and bone formation. Here's an explanation of key aspects of phosphorus:
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