Mass Transfer

Q1: Pick out the correct statement.

A Dialysis process is used for the production of fresh water from brine.

B Electrodylsis is used in the manufacture of NaOH.

C Electrodylsis is used for the refin-ning/purification of petrol.

D both (b) and (c).

ANS:B - Electrodylsis is used in the manufacture of NaOH.

Electrolysis is used in the manufacture of NaOH (sodium hydroxide) through a process known as the chloralkali process. This process involves the electrolysis of a sodium chloride (NaCl) solution, commonly known as brine. Here's how the chloralkali process works:

  1. Electrolysis Cell: The process takes place in an electrolysis cell, which consists of a cathode (negative electrode) and an anode (positive electrode) immersed in a brine solution.
  2. Ion Migration: When an electric current is passed through the brine solution, it undergoes electrolysis. The sodium chloride (NaCl) dissociates into its constituent ions: sodium ions (Na⁺) and chloride ions (Cl⁻).
  3. Ion Discharge: At the cathode, sodium ions (Na⁺) migrate towards the cathode and gain electrons to form sodium metal (Na) according to the half-reaction: 2Na++2e−→2Na2Na++2e−→2Na
  4. Chlorine Production: At the anode, chloride ions (Cl⁻) migrate towards the anode and lose electrons to form chlorine gas (Cl₂) according to the half-reaction: 2Cl−→Cl2+2e−2Cl−→Cl2​+2e−
  5. Hydrogen Production: Additionally, hydrogen gas (H₂) is produced at the cathode due to the reduction of water molecules present in the brine solution: 2H2O+2e−→H2+2OH−2H2​O+2e−→H2​+2OH−
  6. Formation of NaOH: Meanwhile, hydroxide ions (OH⁻) are generated at the cathode due to the reduction of water molecules. These hydroxide ions react with the sodium ions produced at the cathode to form sodium hydroxide (NaOH): Na++OH−→NaOHNa++OH−→NaOH
  7. Separation and Collection: The sodium hydroxide solution (NaOH) is then separated from the brine solution and collected.
Overall, electrolysis in the chloralkali process allows for the production of sodium hydroxide (NaOH) from sodium chloride (NaCl) solution, along with the co-production of chlorine gas (Cl₂) and hydrogen gas (H₂).



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