Chemical Engineering Basics

Q1: Pick out the wrong statement.

A Copper is the metal having the highest electronic conductivity.

B Hardenability & weldability of metals are inversely related.

C Covalant bonding formed by sharing of electrons is present in all semi-conductor materials.

D Glass transition temperature applies to 'polymers' but not to 'glasses'.

ANS:A - Copper is the metal having the highest electronic conductivity.

Glass transition temperature (Tg) is a crucial property in both polymers and glasses. Here's an explanation:

  1. Polymers:
    • In polymers, Tg represents the temperature at which an amorphous polymer transitions from a hard, glassy state to a rubbery or viscous state. Below Tg, the polymer behaves like a rigid solid, while above Tg, it becomes more flexible and exhibits increased molecular mobility.
    • The transition at Tg is associated with the movement of polymer chains from a relatively fixed state to a more mobile state, allowing for increased segmental motion.
  2. Glasses:
    • In glasses, Tg also marks a similar transition from a rigid, amorphous solid to a more flexible state. At temperatures below Tg, glasses are in a solid state and exhibit a rigid structure with limited molecular mobility.
    • As the temperature approaches Tg and surpasses it, the glass undergoes a transition to a softer, more flexible state, characterized by increased molecular motion.
  3. Importance:
    • Tg is an essential parameter in material processing and applications. It influences the mechanical properties, stability, and processability of polymers and glasses.
    • Understanding Tg helps in determining the service temperature range, thermal stability, and processing conditions for polymers and glasses in various applications.
    • For example, in polymer processing, Tg affects the choice of temperature during molding, extrusion, or annealing processes to ensure desired mechanical properties and structural integrity.
In summary, glass transition temperature is a fundamental property that influences the behavior of both polymers and glasses, marking the transition from a rigid to a more flexible state as temperature changes.



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