Chemical Engineering Basics

Q1: Steels with high carbon equivalent have poor weldability, because in these steels during welding

A carbon and other alloying elements get oxidised from the weld pool.

B excessive ferrite forms in the heat affected zone leading to poor toughness of the weld.

C martensite forms in the heat affected zone leading to poor toughness/ductility of the weld.

D segregation of carbon and other element occurs in the weld pool leading to poor properties of the weld.

ANS:C - martensite forms in the heat affected zone leading to poor toughness/ductility of the weld.

Steels with high carbon equivalent have poor weldability primarily because martensite forms in the heat-affected zone leading to poor toughness/ductility of the weld. Explanation:

  1. High Carbon Equivalent: High carbon equivalent in steels indicates a higher carbon content or the presence of other alloying elements that contribute to increased hardenability.
  2. Formation of Martensite: During welding, the high heat input and rapid cooling rates can promote the formation of martensite in the heat-affected zone (HAZ) adjacent to the weld. Martensite is a hard, brittle phase that lacks the toughness and ductility required for most welding applications.
  3. Effect on Weld Properties: The presence of martensite in the HAZ can significantly degrade the mechanical properties of the weld joint. Martensite formation leads to increased hardness and reduced ductility, which can result in weld cracking, brittleness, and poor overall performance.
  4. Other Factors: While oxidation of carbon and alloying elements can occur during welding, excessive ferrite formation, or segregation of carbon and other elements may also contribute to poor weld quality in certain cases. However, the formation of martensite is particularly detrimental to weld properties in steels with high carbon equivalent due to its inherent brittleness.
In summary, the formation of martensite in the heat-affected zone is a key factor contributing to the poor weldability of steels with high carbon equivalent, leading to decreased toughness and ductility of the weld joint.



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