

Stoichiometry - Engineering
Q1: The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. If, at a total pressure of one standard atm. exerted by the vapours of water and toluene, the mole fraction of water Xw in the vapour phase satisfiesA 0 < Xw < 0.5
B Xw = 0.5
C 0.5 < Xw < 1.0
D Xw= 1.0
ANS:C - 0.5 < Xw < 1.0 To solve this problem, we need to consider Raoult's law, which describes the vapor pressure of an ideal solution. According to Raoult's law: 𝑃total=𝑃A⋅𝑋A+𝑃B⋅𝑋BPtotal=PA⋅XA+PB⋅XB Where:
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