Petroleum Refinery Engineering

Q1:

Which is the most ideal feed stock for 'coking' process used for the manufacture of petroleum coke ?

A Naphtha

B Vacuum residue

C Light gas oil

D Diesel

ANS:B - Vacuum residue

The most ideal feedstock for the 'coking' process used for the manufacture of petroleum coke is vacuum residue.

Explanation:

  • Coking Process: This is a thermal cracking process used to convert heavy residual oils into lighter products and petroleum coke. The process operates at high temperatures to break down large hydrocarbon molecules.
  • Vacuum Residue: This is the heavy residue left after vacuum distillation of crude oil. It contains large, complex hydrocarbon molecules that are ideal for coking.

Characteristics of Ideal Feedstock:

  • High Molecular Weight: Vacuum residue consists of large molecules that break down under coking conditions to form lighter hydrocarbons and solid coke.
  • High Carbon Content: This residue has a high carbon-to-hydrogen ratio, which is essential for producing high-quality petroleum coke.
  • Low Value as Fuel: Vacuum residue has limited use as a fuel due to its high viscosity and low volatility, making it more suitable for conversion into valuable products like petroleum coke.

Unsuitable Feedstocks:

  • Naphtha: This is a light, low-boiling fraction used primarily as a feedstock for petrochemical processes or as a blending component in gasoline. It lacks the high molecular weight needed for effective coking.
  • Light Gas Oil: This is a distillate fraction that is typically used as diesel or heating oil. It is not heavy enough for the coking process.
  • Diesel: This is another distillate product, primarily used as a fuel for diesel engines. Like light gas oil, it is not suitable for coking due to its lower molecular weight and boiling range.
Thus, vacuum residue is the preferred feedstock for the coking process to produce petroleum coke.



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