Stoichiometry

Q1: Which of the following is an exothermic reaction ?

A Conversion of graphite to diamond

B Decomposition of water

C Dehydrogenation of ethane to ethylene

D none of these

ANS:D - none of these

  1. Conversion of graphite to diamond:
    • This process involves transforming graphite, which consists of layers of carbon atoms arranged in a hexagonal lattice, into diamond, where carbon atoms are arranged in a three-dimensional tetrahedral lattice.
    • Converting graphite to diamond requires breaking and rearranging chemical bonds in the carbon atoms. This restructuring requires energy input rather than releasing energy, so it's an endothermic process.
    • Therefore, this reaction is endothermic.
  2. Decomposition of water:
    • Water molecules (𝐻2𝑂H2​O) can be decomposed into hydrogen gas (𝐻2H2​) and oxygen gas (𝑂2O2​) through a process known as electrolysis.
    • Electrolysis of water involves passing an electric current through water, causing it to dissociate into hydrogen and oxygen gases.
    • Breaking the bonds in water molecules requires energy input to overcome the bond energies, making this reaction endothermic.
    • Therefore, this reaction is endothermic.
  3. Dehydrogenation of ethane to ethylene:
    • Dehydrogenation is the removal of hydrogen atoms from a molecule.
    • In the dehydrogenation of ethane (𝐶2𝐻6C2​H6​) to ethylene (𝐶2𝐻4C2​H4​), a molecule of ethane loses two hydrogen atoms to form a molecule of ethylene.
    • Breaking the C-H bonds in ethane releases energy, and the formation of C=C double bond in ethylene releases even more energy. Overall, this process releases energy in the form of heat.
    • Therefore, this reaction is exothermic.
In summary, the conversion of graphite to diamond and the decomposition of water are both endothermic reactions because they require energy input, while the dehydrogenation of ethane to ethylene is an exothermic reaction because it releases energy.
 



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